2.3 GHS Label elements, including precautionary statements

Signal word: Warning
Hazard statements:

H242: Heating may cause a fire
H311: Toxic in contact with the skin
H314: Causes severe skin burns and eye damage
H302: Harmful if swallowed

2.4 Precautionary statements
Restriction: 

P264 Wash thoroughly after handing.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves / protective clothing / eye protection / face protection

Compliance:

P312: Call a poison center or doctor/physician if you feel unwell.
P302+P350 IF ON SKIN: Gently wash with plenty of soap and water.
P301+P330+P331 IF SWALLOWED: Rinse mouth. Do not induce vomiting.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Disposal:

P501: Dispose of contents/container by local/national regulations

3. CONSTRUCTION / INFORMATION ON INGREDIENTS OF MSDS

Chemical characterization: Mixtures
Description:
Product: Consisting of the following components.
Note: CAS number is Chemical Abstract Service Registry Number.

4. FIRE-AID FIGHTING MEASURES

4.1 Suitable Extinguishing Media

CO2, dry chemical powder, water spray.

4.2 Specific Hazards Arising from the Chemical

Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Carbon monoxide(CO)
Carbon dioxide
Other irritating and toxic gases.

4.3 Hazardous Combustion LiPoly Battery

Carbon oxides
Explosion Data
Sensitivity to Mechanical Impact: No
Sensitivity to Static Discharge: No

4.4 Protective Devices and Forethoughts for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. For example: Wear self-contained respiratory protective device. Wear suitable protective clothing and eye/face protection.

4.5 Special hazards arising from the substance or mixture:

LiPoly Battery may burst and release hazards decomposition products when exposed to a fire situation. lipoly battery contains the flammable electrolyte that may vent, ignite and produce sparks when subjected to high temperature(>150°C), When damaged or abused(e.g. mechanical damage or electrical overcharging); may burn rapidly with flare-burning effect; may ignite other batteries in clothes proximity.

5. NONESSENTIAL RELEASE MEASURES

5.1 Personal precautions, protective equipment, and emergency procedures

Personal Precautions avoid contact with eyes. Refer to section 8 for personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.

5.2 Environmental forethoughts

Absorb with the liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

5.3 Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up: Use personal protective equipment. Dam up. Cover liquid spill with sand, earth or other Noncombustible absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly.

6. FIRST-AID MEASURES

6.1 First aid measures

Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Skin Contact Remove contaminated clothing and shoes. Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.

6.2 Most important symptoms and effects, both acute and delayed. Swallowing Do not induce vomiting. Get medical attention.

7. HANDLING AND STORAGE

7.1 Forethoughts for safe handling

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment. Wash thoroughly after handling. Use this material with adequate ventilation. The lipoly battery is not explosive.

7.2 Conditions for safe storage, including any incompatibilities

If the LiPoly Battery is subject to storage for such a long term as more than 3 months, it is recommended to recharge the LiPoly Battery periodically.
3 months: -10°C~ +40°C, 45 to 85%RH.
And recommended at 0°C~ +35°C for long period storage.
The capacity recovery rate in the delivery state (50% capacity of fully charged) after storage is assumed to be 80% or more.
The voltage for a long time storage shall be 3.8V ~ 4.8V range.
Do not storage LiPoly Battery haphazardly in a box or drawer where they may short-circuit each other or be short-circuited by other metal objects.
Keep out of reach of children.
Do not expose LiPoly Battery to heat or fire. Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic materials.
Keep ignition sources away – Do not smoke.
Store in cool, dry and well-ventilated place.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

8.1 Instrument Parameters

Ingredients with limit values that require monitoring at the workplace
12190-79-3 Lithium Cobalt Oxide
TLV (USA): 0.02mg/m3
MAK (Germany): 0.1mg/m3
Vacated limits revoked by the court of appeals decision in AFL-CIO OSHS 965 F.2d 962 (11th Cir., 1992)

8.2 Individual protection measures, such as personal protective equipment

Eye/Face Protection
Body protection
Skin protection
Respiratory Protection
Hygiene Measures

4. FIRE-AID FIGHTING MEASURES

4.1 Suitable Extinguishing Media

CO2, dry chemical powder, water spray.

4.2 Specific Hazards Arising from the Chemical

Formation of toxic gases is possible during heating or in case of fire.
In case of fire, the following can be released:
Carbon monoxide(CO)
Carbon dioxide
Other irritating and toxic gases.

4.3 Hazardous Combustion LiPoly Battery

Carbon oxides
Explosion Data
Sensitivity to Mechanical Impact: No
Sensitivity to Static Discharge: No

4.4 Protective Devices and Forethoughts for Firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. For example: Wear self-contained respiratory protective device. Wear suitable protective clothing and eye/face protection.

4.5 Special hazards arising from the substance or mixture:

LiPoly Battery may burst and release hazards decomposition products when exposed to a fire situation. lipoly battery contains the flammable electrolyte that may vent, ignite and produce sparks when subjected to high temperature(>150°C), When damaged or abused(e.g. mechanical damage or electrical overcharging); may burn rapidly with flare-burning effect; may ignite other batteries in clothes proximity.

5. NONESSENTIAL RELEASE MEASURES

5.1 Personal precautions, protective equipment, and emergency procedures

Personal Precautions avoid contact with eyes. Refer to section 8 for personal protective equipment. Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas.

5.2 Environmental forethoughts

Absorb with the liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

5.3 Methods and material for containment and cleaning up

Methods for containment Prevent further leakage or spillage if safe to do so.
Methods for cleaning up: Use personal protective equipment. Dam up. Cover liquid spill with sand, earth or other Noncombustible absorbent material. Pick up and transfer to properly labeled containers. Clean contaminated surface thoroughly.

6. FIRST-AID MEASURES

6.1 First aid measures

Eye Contact Rinse thoroughly with plenty of water, also under the eyelids. If symptoms persist, call a physician. Skin Contact Remove contaminated clothing and shoes. Wash skin with soap and water. In the case of skin irritation or allergic reactions see a physician. Inhalation: Move to fresh air. If symptoms persist, call a physician. Ingestion: Do NOT induce vomiting. Drink plenty of water. If symptoms persist, call a physician.

6.2 Most important symptoms and effects, both acute and delayed. Swallowing Do not induce vomiting. Get medical attention.

7. HANDLING AND STORAGE

7.1 Forethoughts for safe handling

Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes, and clothing. Wear personal protective equipment. Wash thoroughly after handling. Use this material with adequate ventilation. The lipoly battery is not explosive.

7.2 Conditions for safe storage, including any incompatibilities

If the LiPoly Battery is subject to storage for such a long term as more than 3 months, it is recommended to recharge the LiPoly Battery periodically.
3 months: -10°C~ +40°C, 45 to 85%RH.
And recommended at 0°C~ +35°C for long period storage.
The capacity recovery rate in the delivery state (50% capacity of fully charged) after storage is assumed to be 80% or more.
The voltage for a long time storage shall be 3.8V ~ 4.8V range.
Do not storage LiPoly Battery haphazardly in a box or drawer where they may short-circuit each other or be short-circuited by other metal objects.
Keep out of reach of children.
Do not expose LiPoly Battery to heat or fire. Avoid storage in direct sunlight.
Do not store together with oxidizing and acidic materials.
Keep ignition sources away – Do not smoke.
Store in cool, dry and well-ventilated place.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

8.1 Instrument Parameters

Ingredients with limit values that require monitoring at the workplace
12190-79-3 Lithium Cobalt Oxide
TLV (USA): 0.02mg/m3
MAK (Germany): 0.1mg/m3
Vacated limits revoked by the court of appeals decision in AFL-CIO OSHS 965 F.2d 962 (11th Cir., 1992)

8.2 Individual protection measures, such as personal protective equipment

Eye/Face Protection
Body protection
Skin protection
Respiratory Protection
Hygiene Measures

9. STABILITY AND REACTIVITY

9.1 Reactivity

Stable under recommended storage and handling conditions.

9.2 Element stability

Stable under normal conditions of use, storage, and transport.

9.3 Thermal decomposition/conditions to be avoided

No decomposition if used according to specifications.

9.4 The possibility of Hazardous Reactions

None under normal processing.

9.5 Hazardous Polymerization

Hazardous polymerization does not occur.

9.6 Conditions to avoid

Strong heating, fire, Incompatible materials

9.7 Incompatible materials

Strong oxidizing agents. Strong acids. Base metals.

9.8 Hazardous Decomposition Products

Carbon oxides, other irritating and toxic gases.

10. DISPOSAL CONSIDERATIONS

10.1 Waste treatment methods

Recommendation: Must not be disposed of together with household garbage. Do not allow the product to reach the sewage system

10.2 Uncleaned packaging:

Recommendation: Disposal must be made according to official regulations.

11 TRANSPORT INFORMATION

11.1 The LiPoly Battery had been tested according to the requirements of the UN manual of tests and Criteria.

11.2 The LiPoly Battery with a Watt-hour rating not exceeding 100Wh or the cell with a Watt-hour rating in not exceeding of 20Wh.

11.3 Meets the requirements of International Maritime Dangerous Goods(IMDG)-2014 Special Provision 188 to be transported as non-dangerous goods;

11.4 Meets the requirements of 49CFR173.185 to be transported as non-dangerous goods for the road, rail, air, and vessel.

11.5 Meets the requirements of TDG special provision 34 to be transported as non-dangerous goods.

11.6 The package must be handled with care and that a flammability hazard exists if the package is damaged.

11.7 The packaging shall be adequate to avoid mechanical damage during transport, handling and stacking. The materials and pack design shall be chosen so as to prevent the development of unintentional electrical conduction, corrosion of the terminals and ingress of moisture.

12. PHYSICAL AND CHEMICAL PROPERTIES

13. REGULATORY INFORMATION

13.1 Safety, health and environmental regulations/legislation specific to the substance or mixture

13.2 Regulatory information